PokéBase - Pokémon Q&A
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this is on black.

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Toxic Orbs are good, they poison you. (Buy it at the Battle Subway.
Flame Orbs are good, they burn you. (Buy it at the Battle Subway)
Iron Balls are good, it cuts the speed. Also, it makes Flying types vulnerable to Ground moves. (Buy it at the Battle Subway)

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Iron Balls are good to use, but I can't remember exactly how to get it. In D/P/Pt it's somewhere in Iron Island, but I can't remember the specifics. On HG/SS/B/W I have not the slightest clue how I got mine.

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