PokéBase - Pokémon Q&A
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So most of the contacts in my PokeNav have wanted rematches except gym leaders

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You have to defeat the Elite 4 first, then the Gym Leaders will be ready to battle you again.

>In Pokémon Emerald, the Gym Leaders can be rematched through a Double Battle via the PokéNav's Match Call. The player must have defeated the Elite Four.

Hope This Helped :D

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I already beat E4 but none want to  battle
wait. I've matched everyone about 2 times.