PokéBase - Pokémon Q&A
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Done with game

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None of the gym leaders rebattle you in Pokemon white. The only time they battle you is the first time when you get the badge.
Source: experience

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He said nothing about White Version.
it was tagged in the question
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You can't rematch a Gym Leader, except for HG/SS, and, I think just Platinum, where you can find them in the Survival Area (Platinum) or the Fighting Dojo (After obtaining their phone numbers and finding the Karate King).

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