PokéBase - Pokémon Q&A
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I wanna train up to battle battle Red. That guy is OP. :P

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Each Gym Leader is away from their Gym at a certain time of the Day.
Each Gym Leader has a certain day in which if you call them they will Show up in the Fighting Dojo

You need to find them and register their Poke-Gear Number. The Gym Leadera are all scattered around in the Kanto Region.
Here is a list of where you can find them

There are a few exceptions :

Chuck :

Talk to his wife outside his Gym to get the PokéGear number.

LT.Surge:

After you catch Zapdos he will appear in front of the Power Plant.
Show him a Pikachu and he will register you

Blue
Talk to his sister in Pallet Town and get 5 massages from her.
After show her a Pokemon with Max Happiness and she will hand over Blue number e_e
This will help you

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Thanks!!
No problem :D