PokéBase - Pokémon Q&A
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A Riolu is obtainable from a man named Riley in Iron Island,
It might not be a girl but still it has a chance.

(Evolves into Lucario.)


An Eevee is obtainable in Hearthrome City after obtaining the National Dex,
Go to a house with the PC Programmer and she will present you with an Eevee.

To make that Eevee Evolve into Jolteon use a Thunder Stone which you can get by Digging Underground or by obtaining a Poke'Ball in Sunny Shore City.
(Evolves into Jolteon.)
[1]: http://www.pokemonelite2000.com/wp-content/uploads/2011/03/447.gif
[2]: http://www.pokemonelite2000.com/wp-content/uploads/2011/03/133.gif

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You can only find their pre-evouloutions not fully-evolved...
Another Eevee is in the Trophy Gardens.
(Rioulu evolves by hapypnessi
I agree but would like to add that if it is not female, you can always ditto breed.
Ok no prob.