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So just now I was battlin someone on PO and he sane out a heatran, well this was all perectly fine by me until his Heatran used Eruption, and I know for a fact that Heatran can't learn Eruption. How did his Heatran use Eruption? Did he hack PO? Was it a glitch? I am positive it said Eruption, it wasnt Magma Storm, because it let me switch, and it wasn't Overheat, it was Eruption, I am 100% sure. Is it even possible to hack PO?

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maybe it was a zoruark

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Heatran can learn Eruption through an Event in Pokémon Ranger: Guardian Signs in Gen IV.

Source: Bulbapedia/ Eruption
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He even uses it in the Anime:

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cool picture