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I heard this before, but I could use a Master Ball or something. Or, is this encounter like the Ghost Marowak and the Hypno in the GB Kanto games?

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Nope.

You need to separate matches to capture both Zekrom / Reshiram and Kyurem to fuse them with the Gene Wedge.

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Well, yeah, but you can find Black/White Kyurem in the wild in the place where Ghetsis tries to kill you.  Can't you just use a Master Ball then?
The game won't let you use the PokeBall.
Ah.  OK, I get it now.  Weird.