PokéBase - Pokémon Q&A
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I ain't looking for a pkmn that has a 5% chance to appear just for 3 evs but its worth my time if its easy to find. This is for gen 5

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Nothing meets your criteria. The closest I can do is Volcarona, which comes back after defeating the Elite Four after being knocked out.

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So Macho Brace/ Power Item on those that give 2 EVs is your best shot.