PokéBase - Pokémon Q&A
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I was wondering...

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1 Answer

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Yes you can catch the Lake Trio. Mespirit will be roaming around Shinoh, and the other two can be found in the Cave at Lake Variety and Lake Valor.

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What if you beat the other two? I tried to capture them, but the ultra balls wouldn't work...
Then,sorry,that was your first and last chance.