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Okay, so I'm trying to teach my Chikorita baby Magical Leaf and the egg move Ancient Power. Could I breed the Chikorita mother with a Roselia father who knows Magical Leaf to get a baby with Magical Leaf, and then take that baby and breed it with a Tangela/Tangrowth who knows Ancient Power? Then will the next baby Chikorita know Ancient Power and Magical Leaf?

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Nope. You will need to breed AncientPower down from Tangela, Tangrowth, Sheildon, Bastiodon, Cranidos, and Bastiodon, then Level Chikorita to Level 20 to get Magical Leaf and AncientPower. To pass down 2 moves, the male must know both moves. Tangela, Tangrowth, Sheildon, Bastiodon, Cranidos, and Bastiodon don't learn Magical Leaf.

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Ah yes, I forgot this part.
Wait really? I have to just wait for the chikorita to grow up then... Shucks!