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Just Wondering about lucario

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If the Air Balloon pops, and you are not battling someone ingame, the Air Balloon is popped and gone. If you are battling a friend using the Union Room or WiFi, you will get the Balloon back after the battle.

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No. Assuming they used an attacking move that did not miss.

Source: Experience

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An Air Balloon pops when any move that deals damage makes contact; a move like Toxic, Will-O-Wisp etc. won't pop the balloon, nor will a ground-type move, which is an immunity granted by the balloon.

The balloon is a one use item; once popped, it can never be used again.

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