PokéBase - Pokémon Q&A
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Yes it is possible to do so by using certain berries.
You buy the berries in BW2 on Route 5 from a breeder. She'll give you 5 random berries daily.

Pomeg Berry	-10 Hit Point EVs
Kelpsy Berry	-10 Attack EVs
Qualot Berry	-10 Defence EVs
Hondew Berry	-10 Special Attack EVs
Grepa Berry	-10 Special Defence EVs
Tamato Berry	-10 Speed EVs

Source: http://www.serebii.net/games/evs.shtml

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