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My Umbreon with Synchronize held a Flame Orb? Would the opponent be burned?

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No, self-inflicted status won't pass on the opponent. As per Bulbapedia (emphasis mine):

Synchronize can be activated by other Pokémon's Abilities, such as Static, but cannot be activated by the Toxic Orb or Flame Orb.

Synchronize (Ability)

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