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in a episode of pkmn a riolu has aura sphere is that possible to obtained?

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No , a normal Riolu can't learn Aura Shpere.And In the Anime all things can happen.In this case Riolu knows Aura Shere beacuse, according to the anime, it belongs to a Special Kingdom

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http://bulbapedia.bulbagarden.net/wiki/Aura_Sphere_(move) - actually Riolu can know Aura Sphere if it was a special event one in Gen IV; but a normal Riolu cannot learn it via level up.