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in a episode of pkmn a riolu has aura sphere is that possible to obtained?

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In Legends: Arceus, Riolu learns Aura Sphere at Level 21.

In Pokemon Ranger: Shadows of Almia, the mission "Rescue Kidnapped Riolu!" allows players to transfer a Riolu with Aura Sphere to Generation IV games. Though Nintendo has stopped supporting the wi-fi required to access this mission, it can still be obtained via the DNS Exploit.

Aura Sphere (Bulbapedia)

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No , a normal Riolu can't learn Aura Shpere.And In the Anime all things can happen.In this case Riolu knows Aura Shere beacuse, according to the anime, it belongs to a Special Kingdom

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http://bulbapedia.bulbagarden.net/wiki/Aura_Sphere_(move) - actually Riolu can know Aura Sphere if it was a special event one in Gen IV; but a normal Riolu cannot learn it via level up.