PokéBase - Pokémon Q&A
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Iron Tail: yes
Aura Sphere: Yes, but only when obtained from a Gen 4 event.
Double Edge: No

I don't understand so rilou can learn irion tail and aura sphere in generation 6 but not double edge at all right
It can learn Iron Tail, it can only learn Aura Sphere if obtained from the Gen 4 event, and it cannot learn Double Edge.
Wait what do u mean event on gen 4
You can't get Riolu with Aura Sphere anymore, is what I mean.