PokéBase - Pokémon Q&A
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I mean, it's a psychic type,and most psychic types in-game can learn psychic....

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Oops.Sorry!!I wasn't looking over the web page carefully...Sorry!!!

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It can? at level 64 it learns Psychic, it can also learn it through TM as well.

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oh..I mean by TM
it can learn it by TM like pokewatt said
really...Well,I looked at the generation 5 TM learnset for Mewtwo and it isn't there...
EDIT:Well,yes it can..Sorry for the misunderstanding...
Then you must have a faulty web browser or something. I see that Mewtwo can learn Psychic, both at  level 64 and TM 29.
Sorry,I just didn't see it...