PokéBase - Pokémon Q&A
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Yes, you can use any Ball to catch any Pokemon (except when in the Safari Zone or those places where you are given Balls to use). However, if you are asking whether or not it gets the catch rate boost, I am unsure if the area where you catch Zekrom counts towards that.

I was askng if the place its propitious to use it but thnak you anyway
i'm pretty sure the catch boost does count for white...... IF u catch it in N's castle
i catched zekrom in a ultraball