Meta Rate My Team PokéBase - Pokémon Q&A
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To get Chatot in Black, you have to transfer it from a Gen 4 game. Concerning the Master Ball, you can get a second one from a man in the Castelia Pokemon Center after trading with 50 people.
EDIT: Source: http://pokemondb.net/pokedex/chatot
http://bulbapedia.bulbagarden.net/wiki/Master_Ball

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