PokéBase - Pokémon Q&A
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In Pokemon Sapphire/Ruby and Emerald, the only way you can get Relicanth is diving underwater and going through the seawed. This will take some time since there is only a 5% chance of Relicanth appearing compared to the 30% of Chinchou and 65% of Clamperl

Source : http://bulbapedia.bulbagarden.net/wiki/Underwater

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