PokéBase - Pokémon Q&A
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I am trying to figure out which Pokemon to use my master ball with.

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There are numerous legends in B/W 2 that have the lowest catch rate, 3.

  • Kyurem
  • Virizion
  • Terrakion
  • Cobalion
  • Heatran
  • Cresselia
  • Azelf
  • Mesprit
  • Uxie
  • Latios
  • Latias
  • Registeel
  • Regice
  • Regirock

It's all up to you. I would use the Master Ball on the one I want the most, and that's what I recommend doing.

Source: http://bulbapedia.bulbagarden.net/wiki/List_of_Pokémon_by_catch_rate

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