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Is there an item that raises the likelihood of ailments?

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Is there an item that will raise the likelihood of getting burned/paralyzed/poisoned etc...?

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No, there isn't an item that does that.

The ability Serene Grace is the only thing that will increase the chances the secondary effects of a move, i.e. flinch, burn, paralysis etc.

Are there any held items that emulate the 'Serene Grace' ability?

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Thanks!