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In Game for my lead in Wi-fi battles.

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Galvantula learns sticky web at level 65 in X and Y. If your Galvantula is higher than level 65 I suggest taking it to the Move Relearner who is located in Dendemille Town who will reteach you Galvantula sticky web in place of a heart scale.

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Galvantula learns Sticky Web when leveled up to level 65. Source

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