PokéBase - Pokémon Q&A
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Yes, it does.

>The moves Rapid Spin and Defog remove the effect of Sticky Web; Rapid Spin removes Sticky Web set around the user, while Defog removes Sticky Web set on both sides.

Rapid spin affects the following hazards:

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>The moves Rapid Spin and Defog remove the effect of Sticky Web; Rapid Spin removes Sticky Web set around the user, while Defog removes Sticky Web set on both sides.

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