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I have no idea for my Lucario but for Flareon I am leaning towards Lonely or Modest.
Here is a list of natures Please note I am playing White 2 and Y.

Here is her planned moveset.

Flame Charge
Fire Fang
Facade
Iron Tail

As for Lucario, I have just evolved my Riolu. Suggestions for movesets will also be taken in.

Answer if you can!! =]

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Please help me.

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I would suggest Adamant for Flareon, especially since it have access to Flare Blitz in XY. It's Spatk is pretty useless anyway, and it needs the extra power to be useful, and its also not fast enough to sweep in any case, so a tanky variant is preferred.
Lucarios nature depends a lot on what variant you are running since it can be both special and physical. If you want a physical one use Jolly, or use Timid if you prefer a special variant.

Here is a physical moveset:
Lucario
Jolly Nature
- Bullet Punch
- Close Combat
- Swords Dance
- Crunch

Here is a special moveset:
Lucario
Timid Nature
- Aura Sphere
- Hidden Power [Ice]
- Nasty Plot
- Dark Pulse

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For your Flareon I would go for lonely nature as its defense is the lowest stat it has and considering your moveset you have a physical attacker so making it lonely boosts its attack and lowers its defense so when you hit something with an Iron tail etc. then it will do a lot of damge and for your lucario moveset: Dragon pulse , Close Combat/Aura Sphere , Swords Dance ( for the predicted switch ) , and Extreme speed. Nature I would go for a Hasty as its attack and Sp.Attack are already beastly so if you up its speed then you will be able to outspeed alot of Pokemon.

Hope this helped.

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