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Already have Metal Claw down...

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The URL explains everything 4 charizard

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1) Make a male Rampardos, Blastiodon, Tyrantum, Aurorus, or any pre-evolution of the four learn Ancientpower. Levels learned here.

2) Breed a your Ancientpower Pokemon with a female Charizard.

You just hatched an Ancientpower Charizard. I would actually suggest Steel Wing over Metal Claw though, because Steel Wing is more powerful with only 5% less accuracy.

Steel Wing is learned through TM51.

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