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I need to evolve my helioptile.

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There's also one hiding somewhere in Route 13 as well; it's west of the Lumiose City stairs, by a railing.

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In Pokemon Y, you can get a Sun Stones different ways.

  • Tierno will have given you a Peculiar Stone which you can take to Shalour City and trade witha hiker.
  • In a Pokeball along Route 13
  • There is a 5% chance it will be on a Solrock
  • And in the Super Training Game "Drag Down Hydreigon" where you must obtain either a Deino, Zweilous, or Hydreigon Balloon. You might also get Moon Stone from this

Sources: Experience, and this page and this page.

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