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Question says it all...

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It's found in terminus cave

http://www.youtube.com/watch?v=pe5eTyUc2yg

this could help

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Terminus Cave.

Check out this video: http://www.youtube.com/watch?v=pe5eTyUc2yg

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Shadow Ball is located in Terminus Cave
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Do you have to beat the Elite Four first? I was thinking about equipping my Espeon with Shadow Ball for Olympia...