Meta Rate My Team PokéBase - Pokémon Q&A
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So far I have flamethrower, double team, and some other tm.

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Flamethrower, psych up, substitute,and double team

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The Hex Maniac in Anistar City gives you:

TM32 Double Team

TM35 Flamethrower

TM77 Psych Up

TM90 Substitute

For more information and the times need to get them click here.

Hope I helped :)

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Nice one, I actually kinda wanted to know the answer too...
Haha I'm glad I answered then, especially if it's helping others too :)