PokéBase - Pokémon Q&A
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If you have a Pokemon with synchronise as the first Pokemon in your party, then will that Pokemon get the nature of that Pokemon?

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Yes it will have a 50% chance of having the same nature as the Pokemon with synchronize.

///Jofly

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Will the nature be fixed if the Pokemon runs away
thanks
Add in this point: if the pokemon runs away, Synchronize will wear off.