PokéBase - Pokémon Q&A
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Defeating them.

Source- this Bulbapedia page only mentions defeating the Pokemon not winning the battle. (if this source isnt enough, let me know and ill hide)

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it gains evs from fainting the Pokemon. so if you run into a zangoose and seviper horde you can just kill the zangoose for the attack evs and flee the seviper, unless you want the special attack ev too.

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