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TM100 does not exist in the Sinnoh games, so it is impossible to find a TM100. TMs stopped at TM92 (Trick Room) in those games. I guess if you count TMs and HMs together then Rock Climb would be TM100, so in case that's what you meant you can find Rock Climb in Route 217.

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There is no TM 100 in Platinum, Diamond or Pearl.

There is upto TM 92 Trick Room but there is no TM 100. There are 8 HMs too.