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I know Iron Ball + Fling is used a lot, but that's it. Thanks!

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The most Fling damage is Iron Ball.

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Here is a list of useful Items for fling, but Toxic Orb is better than Poison Barb in some cases.

I have been up against only a King's Rock/Razor Claw used for the purpose of Fling.

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I have only seen Kings Rock used
I've seen a dread plate.
A poison barb poisons the opponent, and a Toxic Orb badly poisons the opponent