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I know there are some moves it can't sketch, and that Zinnia says 'It's a move only Rayquaza can learn', but people in the games have also said that about other legendary exclusive moves, and since this is a new move, and it has special effects on Rayquaza, I think I need to ask this question.

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Yes, Smeargle can learn Dragon Ascent via Sketch.
Source: http://www.ign.com/wikis/pokemon-omega-ruby-alpha-sapphire/Compatibility_With_X_and_Y

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Thanks, I was going to check before I tried it myself.
And then you can evolve it into Mega Smearglequaza.
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2/10, Scarf.