PokéBase - Pokémon Q&A
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I was leveling a Pokemon in attack and defense. I maxed out its EVs very quickly. After battles, it would gain 2 in attack after some battles and 3 in attack after others. Do I still need to worry about what Pokemon I'm fighting to get the stats I want?

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No, you do not need to worry. Once you have your EVs maxed out (all 510 of them), then you will not gain EVs from defeated/captured Pokémon.

Source: Experience

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