PokéBase - Pokémon Q&A
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Is there another way to get one besides at Sea Mauville? I'm trying to maximize my breeding efficiency.


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You also get one from a fan in the Contest Hall (note: you have to be master rank for this).
Other than that, no. There's also a small chance that you may get more that one Destiny Knots from the couple at Sea Mauville, or so I've heard.

Hope I helped!

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"or so you've heard." Can anyone confirm this?
Yes I can confirm this.Serebii said so and I saw a guide on how to get the destiny knot on Verlisify's channel
Well I did get that bit of info from a very very unreliable source (my apparent younger brother) so I wasn't too confident :P
What's the chance to get one in the first place? I had to battle them like 12 times for it the first time...