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What Pokemon should I save my master ball for/what Pokemon should I use it on? In Omega Ruby.

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Probably Groudon because it was so hard to catch Kyogre (Alpha Sappire equivilent) even when on 1 HP and Paralyse or Sleep.

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Don't use it unless you have to

Some people find Master Balls highly valuable so don't use it unless you really have to. People will trade legendaries for it.

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Sound advice.
i never used mine in Y but in OR i was lazy when i got to deoxys and just threw it at him to get past him fast