PokéBase - Pokémon Q&A
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In XY, as soon as you catch a second Pokemon, you can trade.
In ORAS, you can only trade after Wally gives you the PlayNavfeature (obtained after he catches Ralts)

Source(s): Serebii, Personal knowledge
-Mega Luxray

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You can trade in X as soon as you catch a second Pokemon.
In OR you can trade after Wally teaches you how to catch a Pokemon

Source(s): XY info, ORAS info

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