PokéBase - Pokémon Q&A
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Title says it all!

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You're asking if something different happens than if you intentionally defeat it?

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If you accidentally KO Lunala / Solgaleo, it will immediately respawn and you can keep KOing it until you catch it.

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Thank you! :3
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I'm pretty sure once you beat the elite 4, it will respawn.

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Thank you! :33