PokéBase - Pokémon Q&A
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You do the same thing you would do to evolve Eevee into Sylveon in Pokémon XY: Let it have a Fairy-type move, raise its affection to 2 hearts in Pokémon Amie, and level it up then.

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Um, excuse my ignorance, but what exactly is Pokémon Amie?
Oh, no problemo. In XY, there is a place where you feed your Pokémon "candy" , play with them, and even pet them.
Ah, OK. I heard it's something similar to Pokémon Refresh in Sun/Moon. Do I access Amie from the game menu or is it a location on the map I have to find?
From the game menu...you will find this.
Amie is accessible from the bottom screen, where the PSS and Super Training are.