PokéBase - Pokémon Q&A
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I need a sun stone in Pokemon black

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In Pokemon Black, the Sun stone can be found in/with/at

Dust clouds, Pickup, Nimbasa City, Relic Castle, Black City, held by wild Solrock

Here is a video showing where to get the one in Relic Castle. Here is the one in Nimbasa.

For a complete list of evolution stones and their locations in the game, check out the Bulbapedia page for it, which is where I got the information above.

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