PokéBase - Pokémon Q&A
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Unnerve is practically useless in competitive battles, as berries are quite rare. Compound Eyes improves the accuracy of moves such as Thunder, which is quite useful for Galvantula.

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In my eyes, Compound Eyes is far more useful. All Unnerve does is keep your enemy from eating berries, and barely any Pokemon in competitive battle uses them. Compound Eyes gives a 30% boost to the accuracy of all moves and in game gives you a higher chance of finding a wild Pokemon with a held item if a Pokemon with this ability is in the front of your party.

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