PokéBase - Pokémon Q&A
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Unnerve is practically useless in competitive battles, as berries are quite rare. Compound Eyes improves the accuracy of moves such as Thunder, which is quite useful for Galvantula.

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Compound eyes for Galvantula used in standarth offensive stances, unnerve for situational/tatical conter tecnique against foes who use berries in their strategies.

(In the second case, NPC's who use berries are mostly the powerfull ones such as the elite four members who use sitrus berries for example or another players in online battles who also have the habbit of use barries in their strategy, such as the typical "snorlax with Chesto berry" for example also)

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In my eyes, Compound Eyes is far more useful. All Unnerve does is keep your enemy from eating berries, and barely any Pokemon in competitive battle uses them. Compound Eyes gives a 30% boost to the accuracy of all moves and in game gives you a higher chance of finding a wild Pokemon with a held item if a Pokemon with this ability is in the front of your party.

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