PokéBase - Pokémon Q&A
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Is it possible to carefully select each item in each area of Lush Jungle in order to avoid battling the other Pokémon?

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If you OHKO it.
I know you can avoid Sudowoodo; there is one tree that looks different than the Sudowoodo. Otherwise, IDK.
Ya I think you can. I'm putting as a comment because I'm pretty sure that I did it myself, but I'm not entirely sure. If you SR Everytime you grab a wrong item I don't think they reset. So just map out the correct items and choose those ones.

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Best answer

Yes. All you have to do is pick the right one, then you will only be able to battle the Totem.

Source: Experience and Bulbapedia

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