PokéBase - Pokémon Q&A
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Why?

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Mew and Ditto can both know Transform, so you’d want them to transform into a really weak Pokémon that can’t harm you while you just throw balls at it. I wouldn’t recommend this for Mew, though, since it’ll probably take out your Magikarp instead of transforming into it.
That, and because it hasn’t been possible to battle a wild Mew since Emerald.

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