PokéBase - Pokémon Q&A
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Like in what situation or route?Or is it in general?Also i think it’s magikarp
All of the routes

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I beileve it’s the Rendezvous Pokémon, Luvdisc

Luvdisc is found at Routes 8 and 12, Ambrette Town, Cyllage City, Shalour City and Azure Bay, when fished up with an Old Rod, which can be obtained early ingame.Luvdisc has a 100% encounter rate when fished

Source:https://m.bulbapedia.bulbagarden.net/wiki/Luvdisc_(Pokémon)

Feel free to criticise

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Whoever voted on this question,  I appreciate your vote very much!
Thats one of the reasons why I don’t fish with an old Rod ;)