PokéBase - Pokémon Q&A
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I don't know everything about Pokeblocks, but I guess you should use 2 different berries, and one should be a Pamtre, Ganlon, or Apicot berry.

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All the berries that make blue/indigo PokéBlocks are:
Chesto Berry - Blue
Oran Berry - Indigo
Lum Berry - Indigo
Bluk Berry - Indigo
Weaper Berry - Indigo
Wiki Berry - Indigo
Kelpsy Berry - Indigo
Hondew Berry - Indigo
Cornn Berry - Indigo
Pamtre Berry

Of all the berries, Wiki, Kelpsy, Hondew, Corrn, and Pamtre are your best options as the others are not as effective and will just waste time and berries.

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