PokéBase - Pokémon Q&A
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Yes. You can use a male Smeargle and Sketch them all and breed with a female Scraggy. That's the only way to get it to learn them all.

Oh snap, i forgot smeargle
I never got a smeargle, before how do you let it sketch moves in the first place?
You have to let a pokemon in a battle use the move you want, and have Smeargle use Sketch in the same turn. Should you mess up, don't worry because he learns the move several times via level up.