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My friend, playing X, caught both Zangoos and Seviper in horde battles, and since I'm doing a professor oak challenge, I'm legally required to catch one if it's the same in this game (oras). Thanks in advance

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Unfortunately (luckily for you), it is not possible to find Zangoose in Alpha Sapphire. It can only be traded from another game.

I hope I helped!

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Can't you find zangoose in serviper hordes and vice versa?
I believed that only applied in X and Y on Route 8.  It says nothing about it on ORAS, but I could be wrong.