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So I finally found a competitively viable Gible, and I was really excited, so I put it in the party to level it up. After a couple of battles, I realised that I completely forgot about EV training. But my Gible hadn't actively participated in a single battle- it was leveling up with the exp share. So I was wondering- would still receive the EVs from those battles?

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Yes.

From Generation V onward, any Pokémon eligible to gain experience, even if they are level 100, gains all EVs awarded from that battle.

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So your Gible definitely received those EVs, so if you want those perfect 252 EVs you'll need to use the EV reducing berries.

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Thanks! I'll find some berries!