Ah how I love Pikalytics :3
I'm going to be honest here... not really.
Let's start with doubles, shall we?
Using stats from Series 6 Battle Stadium Doubles teams with I believe an ELO of 1760+, you won't be seeing Unnerve a lot. Here are the most common Unnerve Pokemon and their ability usage stats:
Corviknight -
Monthly Usage
98k
Usage Percent
13%
Monthly Rank
#11
Mirror Armor 99.674%
Pressure 0.269%
Unnerve 0.056%
Haxorus -
Monthly Usage
8k
Usage Percent
0%
Monthly Rank
#123
Mold Breaker 86.253%
Unnerve 13.574%
Rivalry 0.173%
Galvantula -
Monthly Usage
1k
Usage Percent
0%
Monthly Rank
#192
Compound Eyes 99.094%
Unnerve 0.906%
Persian -
Monthly Usage
301k
Usage Percent
0%
Monthly Rank
#223
Unnerve 94.453%
Technician 5.526%
Limber 0.021%
Bewear -
Monthly Usage
536k
Usage Percent
0%
Monthly Rank
#240
Fluffy 99.968%
Unnerve 0.032%
Klutz 0.000%
Ok so as you can see, Unnerve is outclassed on all of these Pokemon except Persian, which is a very, very rare sight in VGC (plus Alolan Persian greatly outclasses it in the format).
As for the best teams in OU...
Corviknight -
Monthly Usage
402k
Usage Percent
20%
Monthly Rank
#7
Pressure 97.746%
Mirror Armor 2.191%
Unnerve 0.063%
Tyranitar -
Monthly Usage
239k
Usage Percent
12%
Monthly Rank
#17
Sand Stream 99.952%
Unnerve 0.048%
Haxorus -
Monthly Usage
70k
Usage Percent
1%
Monthly Rank
#79
Mold Breaker 96.679%
Rivalry 3.097%
Unnerve 0.224%
Bewear -
Monthly Usage
9k
Usage Percent
0%
Monthly Rank
#100
Fluffy 100.000%
Unnerve 0.000%
Klutz 0.000%
Galvantula -
Monthly Usage
36k
Usage Percent
0%
Monthly Rank
#111
Compound Eyes 90.585%
Swarm 8.827%
Unnerve 0.588%
Surprise! Unnerve is worse in singles!!!
Now, I'll explain why I think Unnerve is very uncommon in both formats.
The Pokemon that get Unnerve aren't very good or common themselves.
- Pokemon such as Persian and Galavntula just aren't that good. While you can't deny that Tyranitar and Corviknight are great Pokemon, the rest of the Unnerve lineup is quite the opposite.
Unnerve is usually outclassed by a Pokemon's other abilities.
- Abilities like Pressure (OU), Mirror Armor (VGC), Fluffy, Compound Eyes, and Sand Stream are just better and more useful than Unnerve, so it is rarely thought about due to being highly outclassed.
Unnerve is very situational.
- Berries, especially in singles, are rare. While Koko used to run a Shuca Berry, that was an exception. I do get that damage-reducing berries are very common in doubles formats, but it's still fairly situational.
So, while Unnerve can be useful, it's very uncommon for the reasons stated above.
Source 1, Source 2
Hope this helps! :)