PokéBase - Pokémon Q&A
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Unfortunately, No. The reason is because Victini, Zacian, Zamazenta, Eternatus, Kubfu/Urishifu, Clayrex, Glastrier, Spectrier, and all three Galarian variants of the Legendary Bird trio are shiny locked, resulting in not being able to get them as shinies. And with that logic, you cannot get a complete Shiny National Pokédex in Pokémon home.

Hope I helped!

Edit: Zacian and Zamazenta are now obtainable as shinies due to an event.

edited by
not yet, anyways
Well yeah
Wait calyrex and glastrier can be shiny?
Oops, forgot those.
victini too, shiny locked
Oh! Right. Sorry, I haven’t played Black/White.
Ok thanks
No problem!